Semiconductor structure and manufacturing method thereof

ABSTRACT

A semiconductor structure includes a semiconductive substrate including a first surface and a second surface opposite to the first surface, a shallow trench isolation (STI) including a first portion at least partially disposed within the semiconductive substrate and tapered from the first surface towards the second surface, and a second portion disposed inside the semiconductive substrate, coupled with the first portion and extended from the first portion towards the second surface, and a void enclosed by the STI, wherein the void is at least partially disposed within the second portion of the STI.

PRIORITY CLAIM AND CROSS-REFERENCE

This application claims the benefit of U.S. provisional application Ser. No. 62/273,808 filed on Dec. 31, 2015, entitled “Semiconductor Structure and Manufacturing Method Thereof”, the disclosure of which is hereby incorporated by reference in its entirety.

BACKGROUND

Electronic equipments using semiconductor devices are essential for many modem applications. With the advancement of electronic technology, the semiconductor devices are becoming increasingly smaller in size while having greater functionality and greater amounts of integrated circuitry. Fabrication of semiconductor devices typically involves placing numerous components over a semiconductor substrate. Isolation structures are used to electrically isolate the components from each other. The components are then interconnected by forming conductive lines over the isolation structures.

Due to the miniaturized scale of the semiconductor device, the components density over the semiconductor substrate continues to increase, while a distance between the components continues to decrease. Numerous manufacturing operations are implemented within such a small semiconductor device, and the formation of the isolation structures becomes challenging. An increase in a complexity of manufacturing the semiconductor device may cause deficiencies such as poor electrical isolation, development of cracks or high yield loss of the semiconductor device. Since more different components with different materials are involved, there are many challenges for modifying a structure of the semiconductor devices and improving the manufacturing operations.

BRIEF DESCRIPTION OF THE DRAWINGS

Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is emphasized that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.

FIG. 1 is a schematic cross sectional view of a semiconductor structure in accordance with some embodiments of the present disclosure.

FIG. 1A is a schematic cross sectional view of a semiconductor structure in accordance with some embodiments of the present disclosure.

FIG. 2 is a schematic cross sectional view of a semiconductor structure in accordance with some embodiments of the present disclosure.

FIG. 2A is a schematic cross sectional view of a semiconductor structure in accordance with some embodiments of the present disclosure.

FIG. 3 is a schematic cross sectional view of a semiconductor structure with one or more dielectric layers in accordance with some embodiments of the present disclosure.

FIG. 4 is a schematic cross sectional view of a semiconductor structure with one or more dielectric layers in accordance with some embodiments of the present disclosure.

FIG. 5 is a schematic cross sectional view of a semiconductor structure with a dielectric liner in accordance with some embodiments of the present disclosure.

FIG. 6 is a schematic cross sectional view of a semiconductor structure with a dielectric liner in accordance with some embodiments of the present disclosure.

FIG. 7 is a schematic cross sectional view of a semiconductor structure with a transistor device and one or more STIs in accordance with some embodiments of the present disclosure.

FIG. 8 is a flow diagram of a method of manufacturing a semiconductor structure in accordance with some embodiments of the present disclosure.

FIGS. 8A-8O are schematic views of manufacturing a semiconductor structure by a method of FIG. 5 in accordance with some embodiments of the present disclosure.

DETAILED DESCRIPTION OF THE DISCLOSURE

The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.

Further, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.

A trench isolation is employed in a semiconductor structure to electrically isolate semiconductor components from each other. The trench isolation is fainted by removing a portion of a semiconductive substrate to form a trench over the semiconductive substrate and then filling the trench with a dielectric material. As the components are close to each other, an undesirable parasitic capacitance would be induced between components. The parasitic capacitance can be minimized by forming an air gap having a low dielectric constant (low k) within the trench isolation, such that an optical crosstalk between components or current leakage would be reduced and sensitivity of the semiconductor structure would be improved.

Further, due to a difference between coefficients of the thermal expansion (CTE) of the semiconductive substrate and the trench isolation, a thermal or mechanical stress would be developed after thermal operations. The air gap can serve as a buffer and reduce stress developed in the semiconductor structure. It is desirable to form the air gap at a position distal to a surface of the semiconductive substrate or at a bottom portion of the trench isolation in order to avoid polysilicon bridging defect. However, a position of the air gap in the trench isolation is difficult to control.

In the present disclosure, a semiconductor structure is disclosed. The semiconductor structure includes a shallow trench isolation (STI) at least partially disposed within a semiconductive substrate and a void enclosed by the STI. The STI includes a first portion tapered into the semiconductive substrate and a second portion coupled with and extended from the first portion into the semiconductive substrate. The first portion is tapered and thus includes at least two widths, and the second portion is extended in a consistent width. Further, a gradient of a sidewall of the second portion is substantially different from or greater than a gradient of a sidewall of the first portion. Such structural configuration of the STI allows the void to be formed at least partially within the second portion of the STI or at a position away from the surface of the semiconductive substrate.

FIG. 1 is a schematic cross sectional view of a semiconductor structure 100 in accordance with some embodiments of the present disclosure. In some embodiments, the semiconductor structure 100 includes a semiconductive substrate 101, a shallow trench isolation (STI) 102 and a void 103. In some embodiments, the semiconductor structure 100 is a part of a semiconductor device. In some embodiments, the semiconductor structure 100 is a part of an image sensing device for sensing an electromagnetic radiation entering into the semiconductor structure 100.

In some embodiments, the semiconductive substrate 101 is a silicon substrate or a silicon wafer. In some embodiments, the substrate 101 includes silicon, germanium, gallium arsenide or other suitable semiconductive materials. In some embodiments, the substrate 101 is a single crystalline or polycrystalline silicon substrate. In some embodiments, the substrate 101 includes several conductive structures, electrical components, etc. In some embodiments, the substrate 101 includes a first surface 101 a and a second surface 101 b opposite to the first surface 101 a. In some embodiments, the first surface 101 a is at a front side of the substrate 101, and the second surface 101 b is at a back side of the substrate 101. In some embodiments, several circuitries or components are subsequently formed over the first surface 101 a.

In some embodiments, the STI 102 is surrounded by or at least partially disposed within the substrate 101. In some embodiments, the STI 102 is configured to electrically isolate components disposed within or over the substrate 101 from each other. In some embodiments, the STI 102 is a trench isolation structure. In some embodiments, the STI 102 includes a dielectric material such as oxide, silicon oxide, etc. In some embodiments, the STI 102 is a dielectric member, an oxide member, etc.

In some embodiments, the STI 102 has a high aspect ratio, for example a width to a height of the STI 102 is about 1:3 to about 1:100. In some embodiments, a height H of the STI 102 is about 300 nm to about 1000 nm. In some embodiments, the height H is about 500 nm to about 800 nm. In some embodiments, the STI 102 is in a funnel or stepped configuration. In some embodiments, the STI 102 includes at least two different widths (W1-1, W1-2 or W2) along its height H. In some embodiments, a sidewall (102 c and 102 d) of the STI 102 disposed between the STI 102 and the substrate 101 includes at least two different gradients, that a portion (for example, 102 c) of the sidewall of the STI 102 is in an angle θ relative to another portion (for example, 102 d) of the sidewall of the STI 102.

In some embodiments, the STI 102 includes a first portion 102 a and a second portion 102 b. In some embodiments, the first portion 102 a is at least partially disposed within the substrate 101 and tapered from the first surface 101 a. of the substrate 101 towards the second surface 101 b of the substrate 101. In some embodiments, the second portion 102 b is disposed inside the substrate 101, coupled with the first portion 102 a and extended from the first portion 102 a towards the second surface 101 b of the substrate 101. In some embodiments, the first portion 102 a is referred as an upper portion of the STI 102, and the second portion 102 b is referred as a lower or bottom portion of the STI 102. In some embodiments, the first portion 102 a is disposed over the second portion 102 b.

In some embodiments, the first portion 102 a includes a first width W1-1 and a second width W1-2 different from the first width W1-1, such that the first portion 102 a is tapered into the substrate 101. In some embodiments, the first width W1-1 is substantially greater than the second width W1-2, or the second width W1-2 is substantially less than the first width W1-1. In some embodiments, the first width W1-1 is about 100 nm to about 500 nm. In some embodiments, the second width W1-2 is about 50 nm to about 250 nm. In some embodiments, a width of the first portion 102 a is gradually decreased from the first width W1-1 to the second width W1-2 along a first height H1 of the first portion 102 a from the first surface 101 a towards the second surface 101 b. In some embodiments, the first portion 102 a has at least two different widths (W1-1 and W1-2) along the first height H1.

In some embodiments, the first portion 102 a includes a first sidewall 102 c extended from the first surface 101 a towards the second surface 101 b or the second portion 102 b. In some embodiments, the first sidewall 102 c is interfaced with the substrate 101 or is between the first portion 102 a and the substrate 101. In some embodiments, the first sidewall 102 c is in an angle β relative to the first surface 101 a. In some embodiments, the angle β is about 5° to 90°. In some embodiments, the angle β is about 15° to 50°

In some embodiments, the second portion 102 b includes a third width W2. In some embodiments, the third width W2 is consistent along a second height H2 of the second portion 102 b from the first portion 102 a of the STI 102 towards the second surface 101 b of the substrate 101. In some embodiments, the second portion 102 b has substantially same width W2 along the second height H2. In some embodiments, the third width W2 of the second portion 102 b is substantially same as the second width W1-2 of the first portion 102 a. In some embodiments, the second portion 102 b is tapered from the first portion 102 a towards the second surface 101 b of the substrate 101. In some embodiments, the second portion 102 b includes at least two widths along its second height H2. In some embodiments, the third width W2 is substantially different from or smaller than the second width W1-2 (for example, as shown in FIG. 1A). In some embodiments, the third width W2 is about 50 nm to about 250 nm. In some embodiments, the second height H2 is substantially greater than the third width W2. In some embodiments, the third width W2 to the second height 1-12 of the second portion 102 b is substantially less than 1:2. In some embodiments, the second height H2 is about 200 nm to about 450 nm. In some embodiments, the second portion 102 b is in a cylindrical shape.

In some embodiments, the second portion 102 b includes a second sidewall 102 d extended from the first portion 102 a towards the second surface 101 b. In some embodiments, the second sidewall 102 d is interfaced with the substrate 101 or is disposed between the second portion 102 b and the substrate 101. In some embodiments, the second sidewall 102 d is substantially orthogonal to the first surface 101 a or the second surface 101 b of the substrate 101. In some embodiments, the second sidewall 102 d is substantially upright. In some embodiments, the second sidewall 102 d is tapered from the first portion 102 a towards the second surface 101 b of the substrate 101.

In some embodiments, the first sidewall 102 c is disposed in angle θ relative to the second sidewall 102 d. In some embodiments, the angle θ is about 1° to 90°. In some embodiments, the angle θ is about 5° to 85°. In some embodiments, the angle θ is about 5° to 85°. In some embodiments, a gradient of the second sidewall 102 d is substantially different from or greater than a gradient of the first sidewall 102 c. In some embodiments, an interior angle α between the first sidewall 102 c and the second sidewall 102 d is substantially greater than 90° but substantially less than 270°. In some embodiments, the interior angle α is about 190° to about 265°.

In some embodiments, the void 103 is enclosed by the STI 102. In some embodiments, the void 103 includes or is filled with air or a material with a dielectric constant (k) of about 1. In some embodiments, the void 103 is in vacuum. In some embodiments, the void 103 is a hollow space inside the STI 102. In some embodiments, the void 103 is at least partially disposed within the second portion 102 b of the STI 102. In some embodiments, the second portion 102 b is hollowed to include the void 103.

In some embodiments, the void 103 is protruded into and partially surrounded by the first portion 102 a of the STI 102. In some embodiments, the void 103 is elongated between the first portion 102 a of the STI 102 and the second surface 101 b of the substrate 101. In some embodiments, the void 103 is in a tear drop shape. In some embodiments, a volume of the void 103 is substantially greater than a volume of the second portion 102 b of the STI 102. In some embodiments, the void 103 is distanced away from a top surface of the STI 102 in a distance D of substantially greater than about 100 nm. In some embodiments, the distance D is about 150 nm to about 500 nm.

FIG. 2 is a schematic cross sectional view of a semiconductor structure 200 in accordance with some embodiments of the present disclosure. In some embodiments, the semiconductor structure 200 includes a semiconductive substrate 101, a shallow trench isolation (STI) 102 and a void 103 which have similar configurations as described above or illustrated in FIG. 1. In some embodiments, the STI 102 of the semiconductor structure 200 includes a first portion 102 a and a second portion 102 b which have similar configurations as described above or illustrated in FIG. 1.

In some embodiments, the first portion 102 a includes a first sidewall 102 c and a bottom sidewall 102 e, and the second portion 102 b includes a second sidewall 102 d. In some embodiments, the first sidewall 102 c of the first portion 102 a and the second sidewall 102 d of the second portion 102 b have similar configurations as described above or illustrated in FIG.

In some embodiments, the bottom sidewall 102 e is disposed in an interior angle ω relative to the first sidewall 102 c. In some embodiments, the angle γ is about 95° to about 175°. In some embodiments, the bottom sidewall 102 e is disposed in an interior angle γ relative to the second sidewall 102 d. In some embodiments, the bottom sidewall 102 e is substantially orthogonal to the second sidewall 102 d. In some embodiments, the angle γ is about 250° to about 270°. In some embodiments, the second portion 102 b includes at least two widths along its second height 112. In some embodiments, the second sidewall 102 d is tapered towards the second surface 101 b of the substrate 101. In some embodiments, the second portion 102 b includes a third width. W2-1 and a fourth width W2-2. In some embodiments, the third width W2-1 is substantially different from or greater than the fourth width W2-2 (for example, as shown in FIG. 2A).

FIGS. 3 and 4 are schematic cross sectional views of a semiconductor structure 300 and a semiconductor structure 400 respectively in accordance with some embodiments of the present disclosure. In some embodiments, the semiconductor structure 300 and the semiconductor structure 400 have similar configurations as the semiconductor structure 100 illustrated in FIG. 1 and the semiconductor structure 200 illustrated in FIG. 2 respectively. In some embodiments, the semiconductor structure 300 and the semiconductor structure 400 respectively include a first dielectric layer 104 and a second dielectric layer 105 are disposed over the substrate 101 and surrounding a portion of the STI 102.

In some embodiments, the first dielectric layer 104 includes dielectric material such as oxide, silicon oxide, etc. In some embodiments, the second dielectric layer 105 includes dielectric material such as nitride, silicon nitride, etc. In some embodiments, the first portion 102 a of the STI 102 is protruded from the substrate 101.

FIGS. 5 and 6 are schematic cross sectional views of a semiconductor structure 500 and a semiconductor structure 600 respectively in accordance with some embodiments of the present disclosure. In some embodiments, the semiconductor structure 500 and the semiconductor structure 600 have similar configurations as the semiconductor structure 100 illustrated in FIG. 1 and the semiconductor structure 200 illustrated in FIG. 2 respectively. In some embodiments, the semiconductor structure 500 and the semiconductor structure 600 respectively include a dielectric liner 106 disposed between the substrate 101 and the STI 102. In some embodiments, the dielectric liner 106 includes dielectric material such as oxide, silicon oxide, etc.

FIG. 7 is a schematic cross sectional view of a semiconductor structure 700 in accordance with some embodiments of the present disclosure. In some embodiments, the semiconductor structure 700 is a part of a circuitry. In some embodiments, the semiconductor structure 700 includes a semiconductive substrate 101, one or more STIs 102, one or more voids 103 enclosed by their respective STIs 102 and a transistor device 701 disposed over or within the substrate 101. In some embodiments, the substrate 101, the STI 102 and the void 103 have similar configurations as described above or illustrated in any one of FIGS. 1-6.

In some embodiments, the substrate 101 is doped with a p-type dopant such as boron or an n-type dopant such as phosphorous to include a source region 703 and a drain region 704. In some embodiments, the source region 703 and the drain region 704 are electrically isolated by the STIs 102. In some embodiments, the transistor device 701 includes a gate structure 702. In some embodiments, the gate structure 702 includes a gate electrode 702 a, a spacer 702 b and a gate dielectric layer 702 c.

In some embodiments, the gate electrode 702 a includes a conductive material such as polycrystalline silicon (polysilicon), aluminum, copper, titanium, tungsten, etc. In some embodiments, the spacer 702 b includes a dielectric material, such as silicon oxide, silicon oxynitride, silicon nitride, a high-k dielectric material (a material with a dielectric constant greater than a dielectric constant of silicon dioxide), etc. In some embodiments, the gate dielectric layer 702 c includes a dielectric material, such as silicon oxide, silicon oxynitride, silicon nitride, a high-k dielectric material, etc.

In the present disclosure, a method of manufacturing a semiconductor structure is also disclosed. In some embodiments, a semiconductor structure is formed by a method. The method includes a number of operations and the description and illustration are not deemed as a limitation as the sequence of the operations. FIG.8 is an embodiment of a method 800 of manufacturing a semiconductor structure. The method 800 includes a number of operations (801, 802, 803, 804 and 805).

In operation 801, a semiconductive substrate 101 is received as shown in FIG. 8A. In some embodiments, the substrate 101 is a silicon substrate or silicon wafer. In some embodiments, the substrate 101 has similar configuration as described above or illustrated in any one of FIGS. 1-7.

In operation 802, a first recess 901 is formed as shown in FIGS. 8B-8D. In some embodiments, a first dielectric layer 104 and a second dielectric layer 105 are disposed over the substrate 101 as shown in FIG. 8B. In some embodiments, the second dielectric layer 105 is disposed over the first dielectric layer 104. In some embodiments, the first dielectric layer 104 and the second dielectric layer 105 disposed over the substrate 101 by any suitable deposition operations such as chemical vapor deposition (CVD), etc. In some embodiments, the first dielectric layer 104 includes oxide, and the second dielectric layer 105 includes nitride.

After the deposition of the first dielectric layer 104 and the second dielectric layer 105, the first dielectric layer 104 and the second dielectric layer 105 are patterned by removing a predetermined portion of the first dielectric layer 104 and the second dielectric layer 105. In some embodiments, the first dielectric layer 104 and the second dielectric layer 105 are patterned by any suitable operations such as photolithography and etching, etc. In some embodiments, a patterned photoresist is disposed over the second dielectric layer 105, such that the predetermined portion of the first dielectric layer 104 and the second dielectric layer 105 is exposed from the patterned photoresist, and then the predetermined portion of the first dielectric layer 104 and the second dielectric layer 105 is removed by any suitable operations such as dry etching, etc. In some embodiments, the first dielectric layer 104 and the second dielectric layer 105 are patterned as shown in FIG. 8C.

After the patterning of the first dielectric layer 104 and the second dielectric layer 105, a first portion 101 a of the substrate 101 corresponding to the predetermined portion of the first dielectric layer 104 and the second dielectric layer 105 is exposed from the first dielectric layer 104 and the second dielectric layer 105 as shown in FIG. 8C. In some embodiments, the first recess 901 is formed by removing the first portion 101 a of the substrate 101 as shown in FIG. 8D. In some embodiments, the first portion 101 a exposed from the patterned first dielectric layer 104 and second dielectric layer 105 is removing by any suitable operations such as dry etching, etc.

In some embodiments, the first recess 901 includes a sidewall 901 a and a bottom surface 901 b. In some embodiments, the sidewall 901 a is a tapered or sloped sidewall tapering from the first surface 101 a into the substrate 101. In some embodiments, the bottom surface 901 b is substantially parallel to the first surface 101 a or the second surface 101 b of the substrate 101. In some embodiments, the first recess 901 includes a first width W1-1 and a second width W1-2 substantially less than the first width W1-1.

In operation 803, a mask layer 108 is disposed over the substrate 101 and along the sidewall 901 a and the bottom surface 901 b of the first recess 901 as shown in FIGS. 8E-8G. In some embodiments, a third dielectric layer 107 is disposed over the second dielectric layer 105 and along the sidewall 901 a and the bottom surface 901 b of the first recess 901 as shown in FIG. 8E. In some embodiments, the third dielectric layer 107 is disposed between the mask layer 108 and the second dielectric layer 105 and the substrate 101. In some embodiments, the third dielectric layer 107 is conformal to the sidewall 901 a, the bottom surface 901 b and the second dielectric layer 105. In some embodiments, the third dielectric layer 107 includes oxide and is disposed by any suitable operations such as CVD, etc.

In some embodiments, the mask layer 108 is disposed over the substrate 101 and within the first recess 901. In some embodiments, the mask layer 108 is disposed over the third dielectric layer 107. In some embodiments, the mask layer 108 includes nitride and is disposed by any suitable operations such as CVD, etc. In some embodiments, a thickness T1 of the mask layer 108 disposed over or adjacent to the sidewall 901 of the first recess 901 is substantially greater than a thickness of the mask layer 108 disposed over the substrate 101 or a thickness T2 of the mask layer 108 disposed over the bottom surface 901 b of the first recess 901. In some embodiments, the mask layer 108 is disposed in a deposition rate faster at or over the sidewall 901 a than at or over the bottom surface 901 b, such that thickness T1 is greater than the thickness T2 as shown in FIG. 8E.

After the deposition of the mask layer 108, a portion of the mask layer 108 disposed over or at the bottom surface 901 b of the first recess 901 is removed as shown in FIG. 8F or 8G. In some embodiments, the portion of the mask layer 108 disposed over the bottom surface 901 b with the thickness T2 is removed to expose a second portion 101 d of the substrate 101.

In some embodiments, the mask layer 108 is partially removed by any suitable operations such as etching, that a whole thickness of the mask layer 108 is reduced (for example, comparison of FIG. 8E and FIG. 8F or 8G). Since the thickness T1 of the mask layer 108 is greater than the thickness T2 of the mask layer 108, the portion of the mask layer 108 disposed over the bottom surface 901 b is completely removed while the mask layer 108 disposed over the sidewall 901 a is still present, that the thickness T1 of the mask layer 108 disposed over the sidewall 901 a is reduced to a reduced thickness T1′ after the partial removal operations of the mask layer 108. As such, the sidewall 901 a of the first recess 901 is still covered by the mask layer 108, while the second portion 101 d of the substrate 101 is exposed from the mask layer 108. In some embodiments, the third dielectric layer 107 disposed over the bottom surface 901 b of the first recess 901 is also removed as shown in FIG. 8F, such that the second portion 101 d of the substrate 101 is exposed from the third dielectric layer 107 and the mask layer 108.

In operation 804, a second recess 902 is formed as shown in FIGS. 8H and 8J or 8I and 8K. In some embodiments, the second portion 101 d of the substrate 101 exposed from the mask layer 108 is removed to form the second recess 902 as shown in FIG. 8H or 8I. In some embodiments, the second portion 101 d is removed by any suitable operations such as dry etching, etc. In some embodiments, the first recess 901 is disposed over and coupled with the second recess 902. In some embodiments, the second recess 902 is extended from the first recess 901 into the substrate 101 towards the second surface 101 b of the substrate 101. In some embodiments, the mask layer 108 and the third dielectric layer 107 are removed by any writable operations such as stripping, etching, etc. as shown in FIG. 8J or 8K after the formation of the second recess 902.

In some embodiments, the second recess 902 is extended in a consistent width W2 along a height H2 of the second recess from the first recess 901. In some embodiments, the width W2 of the second recess 902 is substantially same as the width W1-2 of the first recess 901. In some embodiments, the second recess 902 includes a sidewall 902 a. In some embodiments, the sidewall 902 a is substantially orthogonal to the first surface 101 a or the second surface 101 b of the substrate 101. In some embodiments, the sidewall 901 a of the first recess 901 is tapered towards the second recess 902. In some embodiments, the sidewall 901 a of the first recess 901 is disposed in an angle θ relative to the sidewall 902 a of the second recess 902. In some embodiments, a gradient of the sidewall 901 a of the first recess 901 is substantially different from a gradient of the sidewall 902 a of the second recess 902.

In some embodiments, the first recess 901 includes a bottom sidewall 901 c as shown in FIG. 8K after the removal of the mask layer 108 and the third dielectric layer 107 as shown in FIG. 8I. In some embodiments, the bottom sidewall 901 c is disposed between and is coupled with the sidewall 901 a of the first recess 901 and the sidewall 902 a of the second recess 902. In some embodiments, the bottom sidewall 901 c is substantially orthogonal to the sidewall 902 a. In some embodiments, the bottom sidewall 901 c of the first recess 901 is disposed in an interior angle γ relative to the sidewall 902 a of the second recess 902.

In operation 805, the first recess 901 and the second recess 902 are filled by an oxide material and a void 103 is formed as shown in any one of FIGS. 8L-8O 8K. In some embodiments, the oxide material fills the first recess 901 and the second recess 902 as shown in FIG. 8J or 8K to form a semiconductor structure 300 as shown in FIG. 8L or a semiconductor structure 400 as shown in FIG. 8M respectively. In some embodiments, a 102 is formed after the first recess 901 and the second recess 902 are filled with the oxide material. In some embodiments, the STI 102 includes a first portion 102 a within the first recess 901 and a second portion 102 b within the second recess 902.

In some embodiments, the void 103 is formed within the first recess 901 or the second recess 902 during the filling of the oxide material. In some embodiments, the void 103 is at least partially disposed within the second recess 902. In some embodiments, the semiconductor structure 300 as shown in FIG. 8L has similar configuration as the semiconductor structure 300 as shown in FIG. 3, and the semiconductor structure 400 as shown in FIG. 8M has similar configuration as the semiconductor structure 400 as shown in FIG. 4.

In some embodiments, the oxide material fills the first recess 901 and the second recess 902 as shown in FIG. 8J or 8K to become the semiconductor structure 300 as shown in FIG. 8L or the semiconductor structure 400 as shown in FIG. 8M respectively, and then the first dielectric layer 104 and the second dielectric layer 105 and a top portion of the oxide material out of the first recess 901 are removed by any suitable operations such as stripping, etc. to form a semiconductor structure 100 as shown in FIG. 8N or a semiconductor structure 200 as shown in FIG. 8O respectively.

In some embodiments, the void 103 is formed within the first recess 901 or the second recess 902 during the filling of the oxide material. In some embodiments, the void 103 is at least partially disposed within the second recess 902. In some embodiments, the semiconductor structure 100 as shown in FIG. 8N has similar configuration as the semiconductor structure 100 as shown in FIG. 1, and the semiconductor structure 200 as shown in FIG. 8O has similar configuration as the semiconductor structure 200 as shown in FIG. 2.

In the present disclosure, an improved semiconductor structure is disclosed. The semiconductor structure includes a substrate, a shallow trench isolation (STI) extending into the substrate and a void enclosed by the STI. The STI includes a first portion tapered into the substrate and a second portion extended from the first portion into the substrate. Such structural configuration of the STI allows the void to be formed at least partially within the second portion of the STI or at a position away from the surface of the semiconductive substrate. Therefore, a position of the void can be controlled, such that the void can be formed at least partially within the second portion of the STI as desired.

In some embodiments, a semiconductor structure includes a semiconductive substrate including a first surface and a second surface opposite to the first surface, a shallow trench isolation (STI) including a first portion at least partially disposed within the semiconductive substrate and tapered from the first surface towards the second surface, and a second portion disposed inside the semiconductive substrate, coupled with the first portion and extended from the first portion towards the second surface, and a void enclosed by the STI, wherein the void is at least partially disposed within the second portion of the STI.

In some embodiments, the void is protruded into and partially surrounded by the first portion of the STI. In some embodiments, the first portion of the STI includes a first width and a second width substantially less than the first width, a width of the second portion of the STI is consistent along a height of the second portion from the first portion of the STI towards the second surface of the semiconductive substrate. In some embodiments, the width of the second portion of the STI is substantially same as the second width of the first portion of the STI.

In some embodiments, a sidewall of the STI disposed between the STI and the semiconductive substrate includes at least two different gradients. In some embodiments, the semiconductor structure further includes a first sidewall of the first portion disposed between the semiconductive substrate and the first portion of the STI, and a second sidewall of the second portion disposed between the semiconductive substrate and the second portion of the STI, wherein the first sidewall is disposed in an angle relative to the second sidewall, or a gradient of the second sidewall is substantially different from or greater than a gradient of the first sidewall. In some embodiments, the angle is about 1° to about 85°.

In some embodiments, a ratio of a width of the second portion to a height of the second portion is substantially less than 1:2. In some embodiments, a sidewall of the second portion disposed between the semiconductive substrate and the second portion of the STI is substantially orthogonal to the first surface of the semiconductive substrate. In some embodiments, the STI is in a funnel or a stepped configuration. In some embodiments, the STI includes oxide, or the void includes air or a material with a dielectric constant of about 1 or is in vacuum. In some embodiments, the semiconductor structure further includes a dielectric liner disposed between the semiconductive substrate and the STI.

In some embodiments, a semiconductor structure includes a silicon substrate including a first surface and a second surface opposite to the first surface, an oxide member at least partially disposed within the substrate, and including a first portion extended from the first surface towards the second surface and a second portion disposed inside the substrate, coupled with the first portion and extended from the first portion towards the second surface, wherein the second portion includes a hollow space.

In some embodiments, the hollow space is filled with air or is in vacuum. In some embodiments, the hollow space is elongated between the first portion and the second surface. In some embodiments, a volume of the hollow space is substantially greater than a volume of the second portion of the oxide member.

In some embodiments, a method of manufacturing a semiconductor structure includes receiving a substrate, removing a first portion of the substrate to form a first recess, disposing a mask layer over the substrate and along a sidewall of the first recess and a bottom surface of the first recess, removing a portion of the mask layer disposed over the bottom surface of the first recess, removing a second portion of the substrate exposed from the mask layer to form a second recess, removing the mask layer, filling the first recess and the second recess by an oxide material, and forming a void at least partially disposed within the second recess.

In some embodiments, a thickness of the mask layer disposed over the sidewall of the first recess is substantially greater than a thickness of the mask layer disposed over the substrate or a thickness of the mask layer disposed over the bottom surface of the first recess. In some embodiments, the first recess includes a first width and a second width substantially less than the first width, a width of the second recess is consistent along a height of the second portion from the first recess. In some embodiments, the sidewall of the first recess is tapered towards the second recess, or the sidewall of the first recess is disposed in an angle relative to a sidewall of the second recess, or a gradient of the sidewall of the first recess is substantially different from a gradient of a sidewall of the second recess.

The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure. 

1.-16. (canceled)
 17. A method of manufacturing a semiconductor structure, comprising: receiving a substrate; removing a first portion of the substrate to form a first recess; disposing a mask layer over the substrate and along a sidewall of the first recess and a bottom surface of the first recess; removing a portion of the mask layer disposed over the bottom surface of the first recess; removing a second portion of the substrate exposed from the mask layer to form a second recess; removing the mask layer; filling the first recess and the second recess by an oxide material, and forming a void at least partially disposed within the second recess.
 18. The method of claim 17, wherein a thickness of the mask layer disposed over the sidewall of the first recess is substantially greater than a thickness of the mask layer disposed over the substrate or a thickness of the mask layer disposed over the bottom surface of the first recess.
 19. The method of claim 17, wherein the first recess includes a first width and a second width substantially less than the first width, a width of the second recess is consistent along a height of the second portion from the first recess.
 20. The method of claim 17, wherein the sidewall of the first recess is tapered towards the second recess, or the sidewall of the first recess is disposed in an angle relative to a sidewall of the second recess, or a gradient of the sidewall of the first recess is substantially different from a gradient of a sidewall of the second recess.
 21. The method of claim 17, wherein after the removing the portion of the mask layer and before the removing the second portion of the substrate, the mask layer is disposed on a portion of the bottom surface of the first recess.
 22. The method of claim 17, further comprising: forming a dielectric layer under the mask layer and along the sidewall of the first recess and the bottom surface of the first recess.
 23. The method of claim 22, wherein the removing the portion of the mask layer exposes the dielectric layer.
 24. A method of manufacturing a semiconductor structure, comprising: removing a first portion of a substrate to form a first recess, the first recess having a first width at a top surface and a second width defined by a bottom surface of the first recess, the first width greater than the second width; depositing a mask layer along a sidewall of the first recess and the bottom surface of the first recess; etching the mask layer to expose the bottom surface of the first recess; etching the exposed bottom surface of the first recess to form a second recess connected to the first recess and extending into the substrate while the mask layer is disposed along the sidewalls of the first recess; and after removing the mask layer along the sidewalk of the first recess, depositing a dielectric material in the first recess and the second recess.
 25. The method of manufacturing the semiconductor structure of claim 24, wherein the depositing the mask layer includes forming the mask layer along the sidewall at a greater thickness than along the bottom surface.
 26. The method of manufacturing the semiconductor structure of claim 24, further comprising: forming a dielectric layer along the sidewall of the first recess and the bottom surface of the first recess prior to depositing the mask layer.
 27. The method of manufacturing the semiconductor structure of claim 26, wherein the forming the etching the mask layer exposes the dielectric layer.
 28. The method of manufacturing the semiconductor structure of claim 24, wherein the etching the mask layer decreases a thickness of the mask layer on the sidewall from a first thickness to a second thickness greater than zero.
 29. The method of manufacturing the semiconductor structure of claim 24, wherein the depositing the dielectric material forms a void in the second recess.
 30. The method of manufacturing the semiconductor structure of claim 29, wherein the void extends to the first recess.
 31. The method of manufacturing the semiconductor structure of claim 24, wherein during the etching the exposed bottom surface of the first recess, another portion of the bottom surface of the first recess is covered by the mask layer.
 32. A method of manufacturing a semiconductor structure, comprising: removing a first portion of a substrate to form a first recess, the first recess having a first width at a top surface and a second width defined by a bottom surface of the first recess, the first width greater than the second width; depositing a mask layer along a sidewall of the first recess and the bottom surface of the first recess; etching the mask layer to expose a first region of the bottom surface of the first recess, wherein a second region of the bottom surface and a third region of the bottom surface are covered with the mask layer after the etching, and wherein the first region interposes the second region and the third region; etching the first region of the bottom surface of the first recess to form a second recess connected to the first recess and extending into the substrate while the mask layer is disposed on the second region and the third region; removing the mask layer along the sidewalls and the second region and third region of the bottom surface of the first recess; and depositing a dielectric material in the first recess and the second recess, wherein the dielectric material interfaces with the second region and the third region of the bottom surface of the first recess.
 33. The method of manufacturing a semiconductor structure of claim 32, wherein the depositing the dielectric material includes forming a void within the dielectric material.
 34. The method of manufacturing a semiconductor structure of claim 33, wherein the void extends level with the second region and third region of the bottom surface of the first recess.
 35. The method of manufacturing a semiconductor structure of claim 32, wherein the removing the first portion of the substrate to form the first recess includes forming the sidewall of the first recess having a taper.
 36. The method of manufacturing a semiconductor structure of claim 32, wherein the forming the second recess includes forming sidewalls of the second recess that extend substantially perpendicular to a top surface of the substrate. 